I just saw your question on "Gimme Some Loving;" much of the same stuff applies, so check there first. If the MIDI suggestion works, you can search MusicRobot.com for "Soul Man" MIDIs; and you can search Ultimate-Guitar.com for bass and guitar tabs.
The differences -- I don't think there's any way around getting horns in on this one -- you're gonna need something. Sounds like the Sam and Dave version is using primarily saxophones with at least one trumpet in there; the Blues Brothers generally rocked a pretty full horn section. There are some horn tabs you can find at http://www.horntabs.net/tab/do_search?song=&band=140&type=-1 , which should help. And remember, if you're going to be switching stuff around for instruments -- some of the instruments are inherently in a different key, so you'll have to do some transposition. A C on a trumpet, for instance, is a Bb to a guitar or a piano; and a C on an alto sax (if I recall correctly) is an Eb on a guitar or a piano.
Good luck!
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